charge transport) between the pendant C60 units...The past couple of years have witnessed a remarkable burst in the development of organic field-effect transistors (OFETs), with a number of organic semiconductors surpassing the benchmark mobility of 10 cm2/Vs. Rigorous NMR analysis on a 13C isot...Side-chain manipulation of isoindigo-thiophene derived conjugated polymers was achieved by statistical copolymerization of two different isoindigo monomers decorated with t-Boc groups and polyisobutylene chains, respectively. The properties of the multifunctional polymer can be customized to some extent, such as the excitation wavelength, the emission wavelength, the band gap and the like. Lei Fang was born in Poyang, a medium-sized town located in the southeast of mainland China. The four resultant copolymers were synthesized via palladium Stille cross-cou...The processability and functional performance of stimuli‐responsive supramolecular materials are key factors which determine their utility and potential for mass adoption and profitability. Imparting charge transfer-based functional supramolecular materials with tunable thermochromism, emerges as an ideal strategy to construct optically responsive multifunctional assemblies. Limited solution processability, however, often impedes their practical applications. Bottom-up synthesis and structure-property correlation of these compounds, however, remained challenging. Thicknesses between ∼2-200 nm are achieved. Here, we study how the solution shearing method impacts the thin film morphology and causes structural rearrangements of two polymeric OSCs with interdigitated sidechain packing, name...Supramolecular host-guest chemistry allows sensitive and selective recognition of a certain substrate by using a rationally designed receptor. Wm Michael Barnes ’64 Department of Industrial & Systems EngineeringCopyright © 2019, Texas A&M Engineering Communications, All Rights Reserved 13,32,... Functional organic π-conjugated materials containing polymers, small molecular and oligomers, have received extensive attention from both academic and industrial research laboratories due to their wide applications in optoelectronic devices [1][2][3][4]. You learn the material in this class, and it is also easy to make the grade you want. His notes and examples are directly from the textbook, so if you miss something he said, its easy to go back. He wasn't "inspirational".Tests are straight forward, with a few tricky questions thrown in. The fundamentally important electronic properties of pernigraniline salts - the fully oxidized and acid-doped derivatives of polyanilines, however, are still not well-understood due to their poor stability and configurational uncertainty. In this work, an efficient synthetic route was deve...Well-defined, fused-ring aromatic oligomers represent an important class of molecular candidates for the fundamental understanding and practical applications of advanced carbon-rich materials. However, current organic/inorganic hybrids suffer from inferior thermoelectric properties due to aggregate nanostructures. https://engineering.tamu.edu/industrial/profiles/wang-shiren.html In this work, we discovered a novel version of macrocyclic arenes, namely leaning pillar[6]arenes, which can be considered as a tilted version of pillar[6]arene with two hydroxy/alkoxyl functionalities chopped off. While the problem has attracted adequate attention, current water treatment tools such as commercially available active carbon still can’t satisfy the remediating necessity due to its unfav...Molecular conformation and rigidity are essential factors in determining the properties of individual molecules, the associated supramolecular assemblies, and bulk materials. Go to the SI simply for the review problems if you don't like the SI leader. Fang really knows about ochem, but this semester was wild. Fully conjugated ladder polymers (cLPs), in which all the backbone units on the polymer main-chain are π-conjugated and fused, have attracted great interest owing to their intriguing properties, remarkable chemical and thermal stability, and potential suitability as functional organic materials.

The long polyisobutylene side-chains ensured solution-processability of the polymers while the t-Boc groups served as a clea...In this work, we synthesize large-area thin films of a conjugated, imine-based, two-dimensional covalent organic framework at the solution/air interface. He obtained his BS (2003) and MS (2006) degrees from Wuhan University before movig to the US and receiving his PhD diploma (2010) from Northwestern University. He refuses to use power points (which I liked about him) so you have to be on your toes ready to take good notes. However it is difficult to predict how structural changes to the molecular components of these systems will impact their operation.

This unique approach featured mild conditions and excellent efficiency, affording the ladder polymer backbone with minimum levels of unreacted defects.

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